Rocket fuel
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Used in the production of orbital rockets. As of version 0.13, Rocket fuel can also be used in burner devices to provide 225MJ of energy, however this is slightly less efficient than using 10 solid fuels unless extra products are created using productivity modules.
See also
https://www.reddit.com/r/factorio/comments/4tuhem/is_solid_fuel_more_efficient_than_coal/d5kyrvi Math on producing power from solid/rocket fuel.